Effect of graphene substrate on the SERS Spectra of Aromatic bifunctional molecules on metal nanoparticles

The design of molecular sensors plays a very important role within nanotechnology and especially in the development of different devices for biomedical applications. Biosensors can be classified according to various criteria such as the type of interaction established between the recognition element and the analyte or the type of signal detection from the analyte (transduction). When Raman spectroscopy is used as an optical transduction technique the variations in the Raman signal due to the physical or chemical interaction between the analyte and the recognition element has to be detected. Therefore any significant improvement in the amplification of the optical sensor signal represents a breakthrough in the design of molecular sensors. In this sense, Surface-Enhanced Raman Spectroscopy (SERS) involves an enormous enhancement of the Raman signal from a molecule in the vicinity of a metal surface. The main objective of this work is to evaluate the effect of a monolayer of graphene oxide (GO) on the distribution of metal nanoparticles (NPs) and on the global SERS enhancement of paminothiophenol (pATP) and 4-mercaptobenzoic acid (4MBA) adsorbed on this substrate. These aromatic bifunctional molecules are able to interact to metal NPs and also they offer the possibility to link with biomolecules. Additionally by decorating Au or Ag NPs on graphene sheets, a coupled EM effect caused by the aggregation of the NPs and strong electronic interactions between Au or Ag NPs and the graphene sheets are considered to be responsible for the significantly enhanced Raman signal of the analytes [1-2]. Since there are increasing needs for methods to conduct reproducible and sensitive Raman measurements, Grapheneenhanced Raman Scattering (GERS) is emerging as an important method [3].Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Quantum Hall activation gaps in bilayer graphene

We have measured the quantum Hall activation gaps in bilayer graphene at filling factors $\nu=\pm4$ and $\nu=\pm8$ in high magnetic fields up to 30 T. We find that energy levels can be described by a 4-band relativistic hyperbolic dispersion. The Landau level width is found to contain a field independent background due to an intrinsic level broadening and a component which increases linearly with magnetic field.Comment: 4 pages, accepted version (just removed a few typos), will appear as Fast Track Communication in Solid State Commu

The mycorrhizal status of Phragmites australis in several polluted soils and sediments of an industrialised region of Northern Portugal

Roots of Phragmites australis from three polluted soils and sediments (a periodically flooded stream bank containing organic pollutants, a high-pH drying sedimentation pond and an acidic, periodically flooded sand polluted by industrial effluents) were sampled over a 1-year cycle of plant growth to assess the degree of colonisation by arbuscular mycorrhizal fungi (AMF). At the dry sedimentation pond, root samples of Juncus effusus and Salix atrocinerea were also taken to assess the presence of AMF throughout the year. Root colonisation was low (<5% root length colonised) but arbuscule presence peaked in P. australis during the spring and autumn prior to flowering. These changes in arbuscule abundance were also seen in a parallel greenhouse trial using seed taken from one of the sites. Roots of J. effusus contained mainly vesicular colonisation but arbuscule activity peaked during the winter months (December–March). S. atrocinerea roots were found to be ectomycorrhizal throughout the year but the fine feeder roots were colonised by AMF. The results confirm that semi-aquatics, like P. australis, can become arbuscular mycorrhizal but that this status changes during the year depending on soil moisture content and plant phenology. The influence of AMF in these polluted soils is uncertain but the potential exists to establish a more diverse plant ecosystem during the landscaping of these areas (phytostabilisation) by management of adapted plant and AMF ecotypes

The formation of planetary disks and winds: an ultraviolet view

Planetary systems are angular momentum reservoirs generated during star formation. This accretion process produces very powerful engines able to drive the optical jets and the molecular outflows. A fraction of the engine energy is released into heating thus the temperature of the engine ranges from the 3000K of the inner disk material to the 10MK in the areas where magnetic reconnection occurs. There are important unsolved problems concerning the nature of the engine, its evolution and the impact of the engine in the chemical evolution of the inner disk. Of special relevance is the understanding of the shear layer between the stellar photosphere and the disk; this layer controls a significant fraction of the magnetic field building up and the subsequent dissipative processes ougth to be studied in the UV. This contribution focus on describing the connections between 1 Myr old suns and the Sun and the requirements for new UV instrumentation to address their evolution during this period. Two types of observations are shown to be needed: monitoring programmes and high resolution imaging down to, at least, milliarsecond scales.Comment: Accepted for publication in Astrophysics and Space Science 9 figure

Effect of climatic oscillations on small pelagic fisheries and its economic profit in the Gulf of Cadiz

Several studies have shown the effect of climatic oscillations on fisheries. Small pelagic fish are of special global economic importance and very sensitive to fluctuations in the physical environment in which they live. The main goal of this study was to explore the relationship between the North Atlantic Oscillation (NAO), the East Atlantic pattern (EA), and the Arctic Oscillation (AO) on the landings and first sale prices of the most representative small pelagic commercial species of the purse-seine fisheries in the Gulf of Cadiz (North East Atlantic), the European anchovy Engraulis encrasicolus and the European sardine Sardine pilchardus. Generalised linear models (GLMs) with different data transformations and distribution errors were generated to analyse these relationships. The best results of the models were obtained by applying a moving average of order 3 to the dataset with a double weighted median. Our results demonstrate relationships between NAO, AO, and EA and European anchovy and sardine landings. These cause an indirect effect on the first sale price in markets through catch variations, which affect the price according to the law of supply and demand. The limitations of this study and management implications are discussed.Postprint2,5

A robust model for rapidly varying flows over movable bottom with suspended and bedload transport: modelling and numerical approach

We propose a coupled model for suspended and bedload sediment transport in the shallow water framework. The model is deduced under hydrostatic pressure assumptions and will not assume any Bossinesq hypothesis. The numerical resolution is carried out in a segregated way. First the underlying system of conservation laws is solved by using a first order path-conservative Riemann solver. Then, the source terms corresponding with the erosion and depositions rates are approximated in a semi-implicit way. The final scheme preserves the positivity of the density. Several numerical experiments were carried out in order to validate the model and the numerical scheme. The results obtained are in good agreement with the experimental data

Numerical modelling of the cyclic structural behavior of slender steel members with restrained buckling

Este trabajo presenta un modelo numérico del comportamiento estructural cíclico de barras de pandeo restringido, comúnmente utilizadas como una alternativa a las clásicas barras de arriostramiento concéntrico para protección sismorresistente de pórticos de edificios y otras estructuras. Estos dispositivos se componen normalmente de un núcleo de acero esbelto recubierto por una carcasa de mayor rigidez que tiene por objeto impedir su pandeo cuando se encuentra comprimido. La carcasa puede ser de mortero o de acero, y una interfaz de deslizamiento está interpuesta entre el núcleo y la carcasa para evitar la transferencia excesiva de tensiones tangenciales. El comportamiento del núcleo de acero se describe mediante un modelo de daño y plasticidad, el comportamiento de la carcasa de mortero se describe mediante un modelo de daño isótropo y el comportamiento de la interfaz de deslizamiento se describe mediante un modelo de penalización de contacto. Estos 3 modelos se implementan en el paquete de software Abaqus siguiendo una formulación explícita. En un artículo previo publicado en una revista de ingeniería sísmica se describió someramente el modelo, se comprobó de forma preliminar su capacidad para reproducir el comportamiento cíclico de barras de pandeo restringido y se compararon satisfactoriamente sus resultados con los de ensayos experimentales; el objetivo de este trabajo es describir el modelo en profundidad y discutir en mayor extensión las valoraciones acerca de su utilidad.This work presents a numerical model of the cyclic structural behavior of dissipative buckling-restrained braces, commonly used as an alternative to classical concentric braces for seismic protection of building frames and other structures. Such devices are usually composed of a slender steel core embedded in a stockiest casing that is intended to prevent its buckling when it is under compression. The casing is made either of mortar or steel, and a sliding interface is interposed between the core and the casing to prevent excessive shear stress transfer. The behavior of the steel core is described by a damage and plasticity model; the behavior of the mortar casing is described by an isotropic damage model and the sliding behavior of the interface is described by a contact penalty model. These 3 models are implemented in the Abaqus software package following an explicit formulation. In a previous article (published in an earthquake engineering journal) the model was briefly described, its ability to reproduce the cyclical behavior of buckling-restrained braces was preliminarily pointed out and their results were satisfactorily compared with those of experimental tests. The aim of this paper is to describe the model thoroughly and to present new judgments about its usefulness.Peer Reviewe